This data set contains light absorption coefficients for soluble chromophores (light-absorbing chemicals) and concentrations of hydrogen peroxide (HOOH) and nitrate (NO3-) in ten snow samples that were collected in 2003 at Dome C, Antarctica.
The following example shows how to cite the use of this data set in a publication.
Anastasio, C. and T. Robles. 2012. Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica. Boulder, Colorado USA: National Snow and Ice Data Center. http://dx.doi.org/10.7265/N5MS3QP0.
Platform |
Ground-based Observation |
|---|---|
Liquid Core Waveguide (LCW) Spectrophotometer |
|
Dome C, Antarctica: Northernmost Latitude: 75.1° S |
|
| Austral Summer, 2003 |
|
Wavelength (nm) |
|
Tab-delimited ASCII text (.txt) |
|
Metadata Access |
|
Data Access |
Dr. Cort Anastasio
University of California, Davis
Department of Land, Air, and Water Resources
1 Shields Avenue
Davis, CA 95616
Dr. Tony Robles
University of California, Davis
Department of Land, Air, and Water Resources
1 Shields Avenue
Davis, CA 95616
NSIDC User Services
National Snow and Ice Data Center
CIRES, 449 UCB
University of Colorado
Boulder, CO 80309-0449 USA
phone: +1 303.492.6199
fax: +1 303.492.2468
form: Contact NSIDC User Services
e-mail: nsidc@nsidc.org
This research was supported by National Science Foundation Office of Polar Programs grant number 0230288. The investigators also wish to thank Karen Guldbaek Schmidt, Manuel Hutterli, and Bernhard Stauffer for collecting snow samples and David Paige for manufacturing the LCW adapter assembly.
This data set contains light absorption coefficients for soluble chromophores (light-absorbing chemicals) and concentrations of hydrogen peroxide (HOOH) and nitrate (NO3-), in ten snow samples that were collected in 2003 near Concordia Research Station at Dome C, Antarctica.
The data set consists of two tab-delimted ASCII text files.
Data are available on the FTP site in the ftp://sidads.colorado.edu/pub/DATASETS/AGDC/nsidc0519_anastasio_V01/ directory. This directory contains two data files, Sample_Info.txt and Light_Absorption.txt, and a readme file.
File sizes are 9 KB and 32 KB.
Sample_Info.txt contains concentrations of HOOH and NO3- and site-specific details about the snow samples. Each row represents one sample. Table 2 provides descriptions for the column headings in Sample_Info.txt:
| Column Heading | Description |
|---|---|
| Original_ID | Original sample name assigned by University of Bern |
| UCD_ID | Sample name assigned by University of California, Davis |
| Collection_time | Time sample was collected (local time) |
| Depth_top | Depth at top of sample (cm) |
| Depth_bottom | Depth at bottom of sample (cm)¹ |
| HOOH | Hydrogen peroxide concentration (µmol per liter of melted sample) |
| NO3 | Nitrate concentration (µmol per liter of melted sample) |
| LCW_path | Optical path-length of liquid core waveguide (m) |
| Lat | Latitude of sample location (degrees south) |
| Long | Longitude of sample location (degrees east) |
| Elevation | Elevation of sample location (m) |
| Clean_Area | Indicates whether sample was collected in a designated clean area (Y/N) |
¹If not recorded, a value of 2 cm was estimated for surface samples.
The following is an excerpt from Sample_Info.txt:
Light_Absorption.txt contains the light absorption coefficients for each sample at wavelengths between 240 nm and 640 nm. Table 3 below provides descriptions for the parameters in Light_Absorption.txt:
| Parameter | Description |
|---|---|
| Wavelength | Measurement wavelength (nm) |
| Absorption Coefficient | Absorption (extinction) coefficient (m-1) at the given measurement wavelength¹. Column headings correspond to UCD_ID sample names in Sample_Info.txt. |
¹The relationship between absorption and extinction coefficients is detailed in the Quality Assessment section below.
The following is an excerpt from Light_Absorption.txt:
Figure 1 is a plot of the light absorption coefficients for one sample in Light_Absorption.txt:
All samples were collected near Concordia Research Station at Dome C, Antarctica, at approximately 75.1° S, 123.3° W. Sample_Info.txt contains additional site-specific details for each sample.
Snow samples were collected during the 2003 austral summer.
Files may be downloaded via FTP and accessed using standard spreadsheet software.
Snow samples were collected during the summer of 2003. Although the collection dates were not recorded, samples were likely obtained in January.
All analyses were performed in the Anastasio Research Group laboratory of The University of California, Davis. Nitrate concentrations were measured using ion chromatography with conductivity detection. The detection limit was 500 nanomolar with a precicion of approximately 5%. Hydrogen peroxide concentrations were measured using fluorescence high-pressure liquid chromatography (HPLC) with post-column derivatization. The HPLC detection limit was 10 nanomolar with a precision of approximately 3%.
Absorption coefficients were measured with a custom-built, long path (1.20 m or 1.17 m) liquid-core waveguide placed in a Shimadzu UV-Vis spectrophotometer. The detection limit of the instrument, expressed as an absorption coefficient, is approximately 0.002 m-1. As such, the uncertainy in each absorption coefficient is approximately 0.002 m-1. For additional information about sample processing and analyses, see Anastasio, C. and T. Robles (2007) and Robles, T. et al. (2006).
Absorption coefficients have an uncertainty of approximately 0.002 m-1.
In the original treatment of these data (Anastasio, C. and T. Robles, 2007) the investigators calculated absorption coefficients by subtracting an estimated scattering component from the measured extinction coefficients. The investigators subsequently concluded that scattering in their samples, which were filtered, was negligible and as such the measured extinction coefficients are essentially absorption coefficients.
Anastasio C. and T. Robles. 2007. Light Absorption by Soluble Chemical Species in Arctic and Antarctic Snow, Journal of Geophysical Research, 112(D24304), doi: 10.1029/2007JD008695.
Robles, A., D. Paige, and C. Anastasio. 2006. Lens-Coupled Liquid Core Waveguide for Ultraviolet-Visible Absorption Spectroscopy, Review of Scientific Instruments, 77(073103), doi: 10.1063/1.2219973.
The acronyms used in this document are listed in Table 4.
| Acronym | Description |
|---|---|
| LCW | Liquid-Core Waveguide |
| HPLC | High-Pressure Liquid Chromatography |
| HOOH | Hydrogen Peroxide |
| NO3- | Nitrate |
| UCD_ID | University of California, Davis ID |
| AGDC | Antarctic Glaciological Data Center |
| NSIDC | National Snow and Ice Data Center |
| ASCII | American Standard Code for Information Interchange |
| FTP | File Transfer Protocol |
| Portable Document Format |
June 2012
http://nsidc.org/data/docs/agdc/nsidc0519-anastasio/index.html